multifunction superhydrophobic coatings that facilitate water harvesting are attractive for addressing the daunting water crisis, yet, they are caught in a double bind when their durability is considered, as durable coatings will require both tough micro-textures to survive concentrated stress and high-surface-energy chemistry to form chemical bonds within the matrix. to date, a universal bulk-phase coating that combines multifunctionality, ultra-durability, and fabrication feasibility remains challenging. here, a binary cooperative cell design is reported that can solve the contradiction between the multifunctionality and durability requirements of superhydrophobic coatings. in this strategy, mechanochemically tailored cells with releasable nanoseeds are infused in the common matrix, which serves both as a versatile chemical bridge to achieve strong bonds within the coating building blocks, and as an instantaneous self-repairing generator to improve durability. such a strategy significantly boosted the wear resistance and outdoor stability of the coatings by over 30–100 and 18 folds, respectively, compared with conventional coatings. the coating is applied to the sustainable application, i.e., enhancing the water collection efficiency by at least 1000% even after harsh abrasion. the strategy will broaden the vision in handling the dilemma properties among functional coatings and promote the application of superhydrophobic coatings in extreme environments.
